Riann, an Akaali female
The Akaali was a pre-industrial civilization that the Enterprise NX-01 encountered in 2151, inhabiting a Class M planet. Despite their primitive technological level, their forensic methods were apparently rather impressive, T'Pol and Phlox both expressing admiration for the work of an apothacery owner. Another race, known as the Malurians, were exploiting their planet without their knowledge. The use of tetracyanate 622 caused many of the Akaali to suffer from a serious disease before they were driven off the planet by Enterprise.
Riann was a member of this species. (ENT: "Civilization")